Ammonium bicarbonate, with the chemical formula NH₄HCO₃, is a compound used as an additive to enhance the quality of final products in various industries. It is available in two main grades: industrial (chemical grade) and food grade. It appears as small, white granules or powder and is commonly known as ammonium carbonate or hartshorn. This compound is derived from the reaction between ammonia and carbon dioxide in water, forming a weakly basic bicarbonate salt.
Ammonium bicarbonate is known by several names that reflect its long history of use: ammonium hydrogen carbonate, ammonium acid carbonate, monoammonium carbonate, monoammonium salt of carbonic acid, and powder ammonia.
Traditionally used in baking, particularly in the production of flat baked goods like cookies and crackers, where it reacts with acidic components in the dough to produce carbon dioxide gas, causing the dough to rise.
Used in agricultural applications, particularly in soil improvement and as a component in fertilizers, providing a source of ammonia.
Employed in various chemical processes, including the production of ceramics, paints, pigments, and pharmaceuticals.
Ammonium bicarbonate is generally recognized as safe (GRAS) for use in food by the U.S. Food and Drug Administration (FDA). However, it should be handled carefully as it can release ammonia gas during decomposition, which may irritate the eyes and respiratory system. Ingestion or inhalation of large amounts can be harmful and may cause nausea, vomiting, or respiratory distress. Therefore, appropriate usage and safety precautions should always be followed.
A solution containing ammonium bicarbonate (NH₄HCO₃) typically has a pH ranging from 7.5 to 8.5 when dissolved in water.